THE CORRELATION BETWEEN THE C(2)C(2′) SINGLE BOND LENGTHS OF THE TRANSITION STATES AND BARRIERS TO ROTATION AROUND THE C(2)C(2′) DOUBLE BOND OF GROUND STATES IN THE CONFIGURATIONAL ISOMERIZATION OF 2-ALKYLIDENE-4-OXOTHIAZOLIDINES

17th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings, Volume I) (2024) [G-05-P, pp. 265-268]

AUTHOR(S) / АУТОР(И): Aleksandar Rašović and Vladimir A. Blagojević

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DOI: 10.46793/Phys.Chem24I.264R

ABSTRACT / САЖЕТАК:

Our previous works reported that the barriers to rotation (DG‡) around the C(2)C(2′) double the ground states (GS) as well as C(2)C(2′) single bond lengths of transition states (TS) in the configurational isomerization of thiazolidines 1–2 are efficient parameters using quantifying their push–pull effect both under the same and different solvent conditions. Since they follow similar trends, this work reports achieved good linear correlations between these parameters.

KEYWORDS / КЉУЧНЕ РЕЧИ:

ACKNOWLEDGEMENT / ПРОЈЕКАТ:

This work was supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia (grant no 451-03-66/2024-03/200026).

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