THE C(2)C(2′) SINGLE BOND LENGTHS OF THE TRANSITION STATES IN THE CONFIGURATIONAL ISOMERIZATION OF 2-ALKYLIDENE-4-OXOTHIAZOLIDINES BY THE MEANES TO QUANTIFY THEIR PUSH-PULL EFFECT UNDER SOLVENT CONDITIONS

17th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings, Volume I) (2024) [G-04-P, pp. 261-264]

AUTHOR(S) / АУТОР(И): Aleksandar Rašović and Vladimir A. Blagojević

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DOI: 10.46793/Phys.Chem24I.261R

ABSTRACT / САЖЕТАК:

We reported previously that the barriers to rotation (DG‡) around the C(2)C(2′) double of the selected thiazolidine derivatives 1-2 proved to be an efficient parameter to quantify the push–pull effect of these compounds both under the same and different solvent conditions. As a continuation of the research of potential parameters that could be applied for this purpose, this work explored calculated C(2)C(2′) single bonds of their transition states (TS). Regarding this, they showed to be of great interest.

KEYWORDS / КЉУЧНЕ РЕЧИ:

ACKNOWLEDGEMENT / ПРОЈЕКАТ:

This work was supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia (grant no 451-03-66/2024-03/200026).

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