THE OSCILLATING REACTION DISCOVERED BY W. C. BRAY OCCURS IN HOMOGENEOUS SOLUTION

17th International Conference on Fundamental and Applied Aspects of Physical Chemistry (Proceedings, Volume I) (2024) [D-03-SL, pp. 131-138]

AUTHOR(S) / АУТОР(И): Guy Schmitz

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DOI: 10.46793/Phys.Chem24I.131S

ABSTRACT / САЖЕТАК:

In accordance with the ideas of Bray and Liebhafsky, the oscillating reaction which bears their names occurs in homogeneous solution. Oxygen reactions and the formation of oxygen bubbles produced by the decomposition of H2O2 has an effect but does not explain the oscillations. Any model of the Bray-Liebhafsky reaction must take into account the kinetics of the reactions of iodine compounds with each other and with H2O2. The proposed model explains all the experimental observations including the effects of oxygen, at least semi-quantitatively. The role of radicals during the Bray-Liebhafsky reaction is discussed and a reaction of radical formation in homogeneous solution is proposed.

KEYWORDS / КЉУЧНЕ РЕЧИ:

ACKNOWLEDGEMENT / ПРОЈЕКАТ:

REFERENCES / ЛИТЕРАТУРА:

  • W. C. Bray, J. Am. Chem. Soc., 43(6) (1921) 1262-1267.
  • K. R. Sharma and R. M. Noyes, J. Am. Chem. Soc., 97(1) (1975) 202–204.
  • K. R. Sharma and R. M. Noyes, J. Am. Chem. Soc., 98(15) (1976) 4345–4361.
  • H. A. Liebhafsky, J. Am. Chem. Soc., 53 (1931) 896-911.
  • H. A. Liebhafsky, J. Am. Chem. Soc., 53 (1931) 2074-2090.
  • H. A. Liebhafsky, J. Am. Chem. Soc., 54 (1932) 3499-508.
  • I. Matsuzaki, R. Simic and H.A. Liebhafsky, Bull. Chem. Soc. Jpn., 45(11) (1972) 3367-3371.
  • H. A. Liebhafsky and L.S. Wu, J. Am. Chem. Soc., 96(23) (1974) 7180-7.
  • H. A. Liebhafsky, W. C. McGavock, R. J. Reyes, G. M. Roe and L.S. Wu, J. Am. Chem. Soc., 100(1) (1978) 87-91.
  • H. A. Liebhafsky, R. Furuichi, and G. M. Roe, J. Am. Chem. Soc., 103(1) (1981) 51-56.
  • I. Matsuzaki, T. Nakajima and H. A. Liebhafsky, Chem. Letters, (1974) 1463-1466.
  • S. D. Furrow in Oscillations and Traveling Waves in Chemical Systems, R. J. Field and M. Burger ed., John Wiley & Sons, New York 1985.
  • S.D. Furrow, J. Phys. Chem., 91(8) (1987) 2129-2135.
  • P. Ševčik and L. Adamčiková, J. Phys. Chem. A, 102 (1998) 1288–1291.
  • P. Ševčik, K. Kissimonová, and L. Adamčiková, J. Phys; Chem. A, 104 (2000) 3958-3963.
  • K. Kissimonová, I. Valent, L. Adamčiková and P. Ševčik, Chem. Phys. Lett., 341(2001) 345- 350.
  • E. Szabo and P. Ševčík, J. Phys. Chem. A, 117 (2013) 10604−10614.
  • G. Schmitz, J. Chim. Phys., 84 (1987) 957-965.
  • Lj. Kolar-Anić, Ž. D. Čupić, S. Anić and G. Schmitz, J. Chem. Soc. Faraday Trans., 93 (1997) 2147
  • Ž. D. Čupić, A. Ivanović-Šašić, St. Blagojević, Sl. Blagojević, Lj. Kolar-Anić and S. Anić, Kinet. Mech. Cat., 118 (2016) 27-38.
  • G. Schmitz, Lj. Kolar-Anić, S. Anić and Ž. D. Čupić, J. Phys. Chem.A, 112 (2008)13452- 13457.
  • Lj. Kolar-Anić, Ž. D. Čupić, G. Schmitz and S. Anić, Chem. Eng. Sci., 2010, (65) (2010) 3718-3728.
  • Ž. D. Čupić, V. Marković, A. Ivanović and Lj. Kolar-Anić, in Mathematical Modelling, C. R. Brennan Ed., Nova Science Publishers Inc., New York, 2011, pp. 111-178.
  • G. Schmitz, Phys. Chem. Chem. Phys., 12 (2010) 6605-6615.
  • G. Schmitz, Phys. Chem. Chem. Phys., 13 (2011) 7102-7111.
  • D. R. Stanisavljev, M.C. Milenković, A. D. Popović-Bijelić and M.D. Mojović, J. Phys. Chem. A, 117 (2013) 3292−3295.
  • M. C. Milenković and D. R. Stanisavljev, J. Phys. Chem. A, 116 (2012) 5541−5548.
  • D. R. Stanisavljev, A. Fiona Taylor and I. Nuša Bubanja, Phys. Chem. Chem. Phys., 24 (2022) 14022-14032.
  • D. R. Stanisavljev, A. Fiona Taylor and I. Nuša Bubanja, Phys. Chem. Chem. Phys., 25(29) (2023) 20109-20120.
  • M. Reinhard, G. D. Redden and E. A. Voudrias in „Water Chlorination: Environmental Impact and Health Effects“, Vol. 6, R. L. Jolley Ed., Lewis Publishers 1990, pp 859-870.
  • J. D. Sivey, C. E. McCullough and A. L. Roberts, Environ. Sci. Technol., 44 (2010) 3357– 3362.
  • J. D. Sivey, J. S. Arey, P. R. Tentscher and A. L. Roberts, Environ. Sci. Technol., 47(3) (2013) 1330-1338.
  • M. B. Heeb, J. Criquet, S. G. Zimmermann-Steffens and Urs von Gunten, Water research, 48 (2014) 15-42.
  • G. Schmitz, Z. Noszticzius, G. Hollo, M. Wittmann and S. D. Furrow, Chem. Phys. Lett., 691 (2018) 44-50.
  • S. D. Furrow, and G. Schmitz, Chem. Phys. Lett., 730 (2019) 186-190.
  • D. D. Wagman, W. H. Evans, V. B. Parker, R. H. Schumm, I. Halow, S. M. Bailey, K. L. Churney, and R. L. Nuttall, “The NBS tables of chemical thermodynamic properties,” J. Phys. Chem. Ref. Data 11(Supplement 2), 1982, 1–392.
  • G. Schmitz, Int. J. Chem. Kinet., 40 (2008) 647-652.
  • A. Olexová, M. Mrákavová, M. Melicherčik and L. Treindl, Collect. Czech. Chem. Comm, 71(2006) 91−106.
  • J. Sigalla and C. Herbo, J. Chim. Phys., 54 (1957) 733.
  • G. Schmitz in Proceedings of the 16th Int. Conf. Fundam. Appl. Aspects Phys. Chem., Belgrade, Sept 26-30, Soc. Phys. Chem. Serbia, (2022) 179-186.
  • J. M. Ball and J. B. Hnatiw, Can. J. Chem., 79 (2001) 304-311.
  • G. Schmitz, Russian J. Phys. Chem., 83(9) (2009) 1447-1451.
  • D. A. Armstrong, R. E. Huie, W. H. Koppenol, S. V. Lymar, G. Merényi, P. Neta, B. Ruscic, D.M. Stanbury, S. Steenken and P. Wardman, IUPAC Technical Report, Pure Appl. Chem., 87 (2015) 1139–1150.
  • J. B. Burkholder, S. P. Sander, J. Abbatt, J. R. Barker, C. Cappa, J. D. Crounse, T. S. Dibble, R. E. Huie, C. E. Kolb, M. J. Kurylo, V. L. Orkin, C. J. Percival, D. M. Wilmouth and P. H. Wine, “Chemical kinetics and photochemical data for use in atmospheric studies,” Evaluation No. 19, Jet Propulsion Laboratory, Publication 19-5, Pasadena 2020.
  • A.J. Elliot, Can. J. Chem., 70 (1992) 1658-1651.
  • S. D. Furrow and G. Schmitz, Reac. Kinet. Mech. Cat., 135 (2022) 1163–1170.