Chemia Naissensis Volume 8, No.1 (2025) (str. 1-7)
AUTOR(I) / AUTHOR(S): Gordana Stojanović 
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DOI: https://doi.org/10.46793/ChemN8.1.01S
SAŽETAK / ABSTRACT:
The composition of headspace volatile (HSV) components was determined by direct HS-GC/MS analysis of fresh garlic leaves, stems, and bulbs, as well as granules obtained by extraction of dried bulbs. In all tested samples of fresh garlic parts, the most abundant HSV constituent was diallyl disulfide (65.6 – 46 %), while in granules, diallyl disulfide (27.1 %) and diallyl trisulfide (29.5 %) were the most abundant in approximately equal amounts. It has been shown that automated direct HS-GC/MS analysis can be used to determine volatile constituents of fresh garlic parts and commercial garlic granules.
KLJUČNE REČI / KEYWORDS:
garlic, headspace, GC-MS, sulfides, disulfides, trisulfides
PROJEKAT/ ACKNOWLEDGEMENT:
The author is grateful to the Ministry of Science, Technological Development and Innovation of the Republic of Serbia, for the financial support of this work, within the funding of the scientific research work at the University of Nis, Faculty of Science and Mathematics in Niš (contract number 451-03-137/2025-03/200124).
LITERATURA / REFERENCES:
- Clemente, J. G., Williams, J. D., Cross, M., & Chambers, C. C. (2011). Analysis of garlic cultivars using head space solid phase microextraction/gas chromatography/mass spectroscopy. The Open Food Science Journal, 6, 1-4. https://doi.org/10.2174/1874256401206010001
- El-Saber Batiha, G., Magdy Beshbishy, A., Wasef, L., Elewa, Y. H. A., A Al-Sagan, A., Abd El- Hack, M. E., Taha, A. E., Abd-Elhakim, Y., & Prasad Devkota, H. (2020). Chemical Constituents and Pharmacological Activities of Garlic (Allium sativum L.): A Review. Nutrients, 12(3), 872- 893. https://doi.org/10.3390/nu12030872).
- Jiménez-Amezcua, I., Luz Sanz, M., Díez-Municio, M., Parker, J. K., Oruna-Concha, M. J., & Soria, A. C. (2025). Changes in the bioactive content and aroma profile of aged garlic with processing conditions. LWT – Food Science and Technology, 227,118003. https://doi.org/10.1016/j.lwt.2025.118003.
- Jovanović, S. Č., Jovanović, O. P., Mitić, Z. S., Petrović, G. M., & Stojanović, G. S. (2020). Chemical composition and distribution of the headspace volatiles in commercial culinary herbs and spices: Chemometric approach. Journal of the Serbian Chemical Society, 85(8), 1001–1010. https://doi.org/10.2298/JSC191121007J
- Keleş, D., Taşkin, H., Baktemur, G., Kafkas, E., & Büyükalaca, S. (2014). Comparitive study on volatile aroma compounds of two different garlic types (Kastamonu and Chinese) using gas chromatography mass spectrometry (HS-GC/MS) technique. African journal of traditional, complementary, and alternative medicines: AJTCAM, 11(3), 217–220. https://doi.org/10.4314/ajtcam.v11i3.30
- Molina-Calle, M., Priego-Capote, F., & de Castro, M. D. (2016). HS-GC/MS volatile profile of different varieties of garlic and their behavior under heating. Analytical and Bioanalytical Chemistry, 408(14), 3843–3852. https://doi.org/10.1007/s00216-016-9477-0
- Najman, K., Król, K., & Sadowska, A. (2022). The Physicochemical Properties, Volatile Compounds and Taste Profile of Black Garlic (Allium sativum L.) Cloves, Paste and Powder. Applied Sciences, 12(9), 4215-4234. https://doi.org/10.3390/app12094215
- Radulović, N., Miltojević, A., Stojković, M., & Blagojević, P. (2015). New volatile sulfur- containing compounds from wild garlic (Allium ursinum L., Liliaceae). Food Research International, 78, 1-10. https://doi.org/10.1016/j.foodres.2015.11.019.
- Warren, J. M., Parkinson, D. R., & Pawliszyn, J. (2013). Assessment of thiol compounds from garlic by automated headspace derivatized in-needle-NTD-GC-MS and derivatized in-fiber- SPME-GC-MS. Journal of Agricultural and Food Chemistry, 61(3), 492–500. https://doi.org/10.1021/jf303508m
