Multi-element analysis of methanol apple peel extracts by inductively coupled plasma-optical emission spectrometry

Chemia Naissensis Volume 3, No.2 (2020) (стр. 67-88) 

АУТОР(И) / AUTHOR(S): Snežana S. Mitić, Branka T. Stojanović, Milan N. Mitić, Aleksandra N.Pavlović, Biljana Arsić, Vesna Stankov-Jovanović

Е-АДРЕСА / E-MAIL: mitich_s@yahoo.com

Download Full Pdf   

DOI: 10.46793/ChemN3.2.067M

САЖЕТАК / ABSTRACT:

Apples are among the most popular fruits in the world. They are rich in phenolic compounds, pectin, sugars, and a vast number of inorganics beneficial for the human health. In this study, variations of macroelements and microelements contents of five different apple cultivars peel’s methanol extracts from Serbia were investigated, using inductively coupled plasma-optical emission spectrometry and principal component analysis (PCA). Regarding macro elements, K, Na, Ca and Mg are with the highest contents. The most abundant essential element is Fe. Among toxic and potentially toxic elements, only the presence of Al and Sr is registered. The analyzed samples are classified into five groups by PCA.

КЉУЧНЕ РЕЧИ / KEYWORDS:

macroelements, microelements, methanol extract, apple cultivars

ЛИТЕРАТУРА / REFERENCES:

  • Addinsoft, 2014. XLSTAT 2014: Data analysis and statistical solution for Microsoft Excel. Addinsoft, Paris.
  • Bakkali, K., Martos, N.R., Souhail, B., & Ballesteros, E. (2009). Characterization of trace metals in vegetables by graphite furnace atomic absorption spectrometry after closed vessel microwave digestion. Food Chemistry, 116, 590–594.
  • Beattie, J.K., & Quoc, T.N. (2000). Manganese in pineapplejuices. Food Chemistry, 68, 37-39.
  • Bo S., & Pisu E. (2008). Role of dietary magnesium in cardiovascular disease prevention, insulin sensitivity and diabetes. Current Opinion in Lipidology, 19, 50–56.
  • Carrera, C., Ruiz-Rodríguez, A., Palma, M. & Barroso, C.G. (2012). Ultrasound assisted extraction of phenolic compounds from grapes. Analytica Chimica Acta, 732, 100-104.
  • Dehelean, ,  &  Magdas,  D.A.   (2013).   Analysis   of   mineral   and   heavy   metal   content   of some commercial fruit juices by inductively coupled plasma mass spectrometry. The Scientific World Journal, http://dx.doi.org/10.1155/2013/215423
  • Ekinci, C., & Koklu, U. (2000). Determination of vanadium, manganese, silver and lead by graphite furnace atomic absorption spectrometry after preconcentration on silica-gel modified with 3- aminopropyltriethoxysilane. Spectrochimica Acta Part B, 55, 1491-1495.
  • Froes, R.E.S., Neto, W.B., Silva, N.O.C., Naveira, R.L.P., Nascentes, C.C., & Silva, J.B.B. (2009). Multivariate optimization by exploratory analysis applied to the determination of microelements in fruit juice by inductively coupled plasma optical emission spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy, 64, 619-622.
  • Hague, T., Petroczi, A., Andrew, P.L.R., Barker, J., & Naughton, D.P. (2008). Determination of metal ion content of beverages and estimation of target hazard quotients: a comparative study. Chemistry Central Journal, 2, 1–9.
  • Hall J.E. (2003). The kidney, hypertension, and obesity. Hypertension, 41, 625–633.
  • Horel, J. D. (1981). A rotated principal component analysis of the interannual variability of the northern hemisphere 500 mb height field. Monthly Weather Review, 109, 2080-2092.
  • Horel, J.D. (1984). Complex principal component analysis: theory and examples. Journal of Climate and Applied Meteorology, 23, 1660-1673.
  • Huskisson E., Maggini S., & Ruf M. (2007). The role of vitamins and minerals in energy metabolism and well-being. Journal of International Medical Research, 35, 277–289.
  • Kitanovic, ,  Milenovic,  D.,  &Veljkovic,  V.B.  (2008).  Empirical   kinetic   models   for   the  resinoid extraction from aerial parts of St John’s Wort (Hypericum perforatum L.). Biochemical Engineering Journal, 41, 1–11
  • Ko, E.A., Han, J., Jung, I.D., & Park W.S. (2008). Physiological roles of K+channels in vascular smooth muscle cells. Journal of Smooth Muscle Research, 44, 65–81.
  • Lambert, I.H., Hoffmann, E.K., & Pedersen S.F. (2008). Cell volume regulation: Physiology and pathophysiology. Acta Physiologica 194, 255–282.
  • López, F.F., Cabrera, C., Lorenzo, M.L., & López, M.C. (2002). Aluminium content of drinking waters, fruit juices and soft drinks: contribution to dietary intake. Science of the Total Environment, 292, 205- 213.
  • Martinez-Ballesta, M.C., Dominguez-Perles, R., Moreno, D.A., Muries, B., Alcaraz-Lopez, C., Bastias, E., Garcia-Viguera, C., & Carvajal, M. (2010). Minerals in plant food: effect of agricultural practices and role in human health. A review. Agronomy for Sustainable Development, 30, 295–309.
  • Micić, R.J., Dimitrijević, D.S., Kostić, D.A., Stojanović, G.S., Mitić, S.S., Mitić, M.N., Pavlović, A.N., & Ranđelović, S.S. (2013). Content of heavy metals in mulberry fruits and their extracts-correlation analysis. American Journal of Analytical Chemistry, 4, 674-682.
  • Milić, P.S., Rajković, K.M., Bekrić, D.M., Stamenković, O.S., & Veljković, V.B. (2014). The kinetic and thermodynamic analysis of ultrasound-extraction of minerals from aerial parts of white lady’s bedstraw (Galium mollugo ). Chemical Engineering Research and Design, 92, 1399–1409.
  • Mitić, S., Stojanović, B., Tošić, S., Pavlović, A., Kostić, D., & Mitić, M. (2019). Comparative study on minerals in peel and pulp of peach (Prunus persica ) fruit. Revista de Chimie, 70, 2281-2285.
  • Mitic, S.S., Obradovic, M.V., Mitic, M.N., Kostic, D.A., Pavlovic, A.N., Tosic, S.B., & Stojkovic, M.D. (2012). Elemental composition of various sour cherry and table grape cultivars using inductively coupled plasma atomic emission spectrometry method (ICP-OES). Food Analytical Methods, 5, 279–286.
  • Morgan K.T. (2008). Nutritional determinants of bone health. Journal of Nutrition for the Elderly, 27, 3– 27.
  • Pednekar, P.A., & Raman, B. (2013). Multielement determination in methanolic Soxhlet leaf extract of Semecarpus anacardium (Linn. F.) by ICP-AES technique. Asian Journal of Pharmaceutical and Clinical Research, 6, 132-137.
  • Petenatti, M.E., Petenatti, E.M., Del Vitto, L.A., Téves, M.R.T., Caffini, N.O.K., Marchevsky, E.J., & Pellerano, R.G. (2011). Evaluation of macro and microminerals in crude drugs and infusions of five herbs widely used as sedatives. Revista Brasileira de Farmacognosia Brazilian Journal of Pharmacognosy, 21, 1144-1149.
  • Renkema, K.Y., Alexander, R.T., Bindels, R.J., & Hoenderop, J.G. (2008). Calcium and phosphate homeostasis: Concerted interplay of newregulators. Annals of Medicine, 40, 82–91.
  • Savić, S.R., Petrović, S.M., Stamenković, J.J., & Petronijević, Ž.B. (2015). The presence of minerals in clear orange juices. Advanced technologies, 4, 71-78.
  • Sobotka L., Allison S., & Stanga, Z. (2008). Basics in clinical nutrition: Water and electrolytes in health and disease. e-SPEN, 3, 259–266.
  • Stojanović, B.T., Mitić, S.S., Mitić, M.N., Paunović, D.Đ., Arsić, B.B., & Stojanović, G.S. (2014). The multielement analysis of the apple peel using the ICP-OES method. Advanced technologies, 3, 96-104.
  • Stojanović, B.T., Mitić, S.S., Stojanović, G.S., Mitić, M.N., Kostić, D.A., Paunović, D.Đ., Arsić, B.B., & Pavlović, A.N. (2017). Phenolic profiles and metal ions analyses of pulp and peel of fruits and seeds of quince (Cydonia oblonga ). Food Chemistry, 232, 466-475.
  • Szefer, P., & Grembecka M. (2007). Mineral components in food crops, beverages, luxury food, species, and dietary food, in: Szefer, P., Nriagu, J.O. (Eds.), Chemical and functional properties of food components series,     CRC     Press,     Taylor     and     Francis     Group,     New     York,     USA,     231–322.
  • Tormen, L., Torres, D.P., Dittert, I.M., Araujo, R.G.O., Frescura, V.L.A., & Curtius, A.J. (2011). Rapid assessment of metal contamination in commercial fruit juices by inductively coupled mass spectrometry after a simple dilution. Journal of Food Composition and Analysis, 24, 95–102.
  • Velimirović, D., Mitić, S., Tosić, S., Pavlović, A., & Stojković, M. (2013). Determination of the content of some trace elements in particular samples of grains, flours and breads by ICP-OES. Oxidation Communications, 35, 160 –
  • Wang, L., & Weller, C.L. (2006). Recent advances in extraction of nutraceuticals from plants. Trends in Food Science & Technology, 17, 300–312.
  • Williams, F.H. (2008). Neuromuscular complications of nutritional deficiencies. Physical Medicine and Rehabilitation Clinics of North America, 19, 125–148.