AUTHOR(S) / АУТОР(И): Jovana Cvjetković, Darko Manjenčić, Vladan Mićić, Anja Manjenčić
E-MAIL:
DOI: 10.46793/SBT29.59JC
ABSTRACT / САЖЕТАК:
For everyone involved in the synthesis, processing and application of elastomers, it is necessary to know how an elastomeric material will behave under the influence of different types of energy. The aim of this work is to establish the resistance of biocompatible silicone elastomers to the permitted doses of radiation. Elastomeric materials were irradiated with gamma rays in a Co-60 radiation chamber with a dose of 25 kGy/h. By determining the various properties before and after irradiation of the silicone material, it was found that the resistance to radiation is significantly improved in samples reinforced with silicon (IV) oxide nanoparticles. FTIR spectroscopy was used to confirm the assumed mechanism of the crosslinking reaction of siloxane. The analysis of the thermal properties of the synthesized siloxane materials was performed using a DSC device, which showed that the proportion of nanofillers and vinyl functional groups significantly affects the values of the melting temperatures before and after irradiation.
KEYWORDS / КЉУЧНЕ РЕЧИ:
REFERENCES / ЛИТЕРАТУРА:
- Bhattacharya A., (2000). Radiation and Industrial Polymers, Progress in Polymer Science. Vol. 25 371-400.
- Davenas J., Stevenson I., Celette N., Cambon S., Gardette J., Rivaton A., Vignoud L., (2002). Stability of Polymers under Ionising Radiation: The Many Faces of Radiation Interactions with Polymers, Nuclear Instruments and Methods in Physics Research Section B. Vol 191 653-661.
- Ivanov V., (1992). Radiation Chemistry of Polymers, VSP, Utrecht, 7-295.
- Woods R., Pikaev A., (1994). Applied Radiation Chemistry: Radiation Processing, John Wiley & Sons, New York, 272-391.
- Ren J., Liu Y, Tang X., (2003). Preparation, properties and application of polymeric organic-inorganic nanocomposites, Chinese Journal of Chemical Engineering., Vol-11 326-333.
- Liu T., Burger C., Chu B., (2003). Nanofabrication in polymer matrices, Progress in Polymer Science, Vol. 28 5-26.
- Kickelbick G., (2003). Concepts for the incorporation of inorganic building blocks into organic polymers on a nanoscale, Progress in Polymer Science, Vol. 28 83-114.
- Zhao Q., Chen W., Zhu Q., (2003). Preparation of nanoporous SiOx materials via interpenetrating polymer network method, Materials Letters, 57 3606-3608.
- Kanar N., (2006). Silicone PSAs: Trends in the east and west. 29th Pressure Sensitive Tape Council Technical Seminar. Las Vegas.
- Okumura Y., Ito, K., (2001). The polyrotaxane gel: a topological gel by figure-of-eight crosslinks. Adv. Mater, 13, 485–487.
https://doi.org/10.1002/15214095(200104)13:7%3C485::AID-ADMA485%3E3.0.CO;2-T - Sanchez, C., Ribol, F., (1994). Design of hybrid organic-inorganic materials synthesized via solgel chemistry. New Journal of Chemistry, 18(10), 1007–1047.