AMBALAŽA NA BAZI CELULOZE, TEMPO OKSIDISANIH CELULOZNIH NANOFIBRILA I HITOZANA ZA PRODUŽENJE ROKA ODRŽIVOSTI HRANE

CPAG (2024),  (стр. 11-18)

АУТОР(И) / AUTHOR(S): Matea Korica, Mirjana Kostić

Download Full Pdf   

DOI: 10.46793/CPAG24.011K

САЖЕТАК / ABSTRACT:

Modern food packaging no longer only plays a passive role in protecting and selling food, but actively changes the state of the packaged food in order to extend its shelf life. From that aspect, packaging based on cellulose, TEMPO-oxidized cellulose nanofibrils (TOCN), and chitosan, has great application potential. In this work, ultra-thin films (thickness below 100 nm) based on cellulose, TOCN, and chitosan were made to serve as a general model for packaging based on cellulose, TOCN, and chitosan. Using a quartz crystal microbalance with dissipation (QCM-D), it was investigated how TOCN coating affects the water absorbance capacity of cellulose-based ultra-thin films, as well as at which pH values greater chitosan adsorption occurs on ultra-thin films based on cellulose and TOCN. The bio-activity of the multilayered thin films was evaluated in vitro against Staphylococcus aureus and Escherichia coli. The multifunctionality comprising high water absorbance capacity and antimicrobial activity, recommend such polysaccharide-based thin films for food packaging applications.

КЉУЧНЕ РЕЧИ / KEYWORDS:

packaging, cellulose, TEMPO-oxidized cellulose nanofibrils, extendrd shelf life of food

ЛИТЕРАТУРА / REFERENCES:

  • Lazić, , Gvozdenović, J. & Petrović, T. Mogućnosti savremenog pakovanja hrane. Časopis za procesnu tehniku i nergetiku u poljoprivredi/PTEP 12(1-2), 49-52 (2008).
  • Ivanković, Aktivna ambalaža na bazi biopolimera za pakiranje hrane, Završni rad, Fakultet kemijskogi nženjerstva i tehnologije, Sveučilište u Zagrebu, (2023). https://urn.nsk.hr/urn:nbn:hr:149:129600
  • Boras, Primjena biorazgradivog pakiranja hrane I utjecaj na rok trajnosti s obzirom na njihovu razgradivost, Doktorska disertacija, Prehrambeno-biotehnološki fakultet, Sveučilište u Zagrebu (2020). https://urn.nsk.hr/urn:nbn:hr:159:292615
  • Tarrés, , Oliver-Ortega, H., Ferreira, P. J., ÀngelsPèlach, M., Mutjé, P. & Delgado-Aguilar, M. Towards a new generation of functional fiber-based packaging: cellulose nanofibers for improved barrier, mechanical and surface properties. Cellulose 25, 683-695 (2018).
  • Cheng, , Li, J., Su, M., Xiao, N., Zhong, L., Zhang, X., Chen, S., Chen, Q., Liang, W. & Liu, M. High-Barrier Oxidized Cellulose Nanofibril/Chitosan Coating for Functional Food Packaging Materials. ACS Applied Polymer Materials 6(5), 2877–2888 (2024).
  • Isogai, , Saito, T. &Fukuzumi, H. TEMPO-oxidized cellulose nanofibers. Nanoscale 3, 71–85 (2011).
  • Levanič, , Svedström, K., Liljeström, V., Šernek, M., Osojnik Črnivec, I. G., PoklarUlrih, N. & Haapala, A. Cellulose fiber and nanofibril characteristics in a continuous sono-assisted process for production of TEMPO-oxidized nanofibrillated cellulose. Cellulose 29(17), 9121-9142 (2022).
  • Zemljič, F., Valh, J. V. &Kreže, T. Preparation of antimicrobial paper sheets using chitosan. Cellululose Chemistry and Technology 51, 75-81 (2017).
  • Cabañas-Romero, V., Valls, C., Valenzuela, S. V., Roncero, M. B., Pastor, F. J., Diaz, P. & Martínez, J. Bacterial cellulose–chitosan paper with antimicrobial and antioxidant activities. Biomacromolecules 21(4), 1568-1577 (2020).
  • Korica, Dobijanje bioaktivnih nanostrukturnih materijala na bazi celuloze i hitozana, Doktorska disertacija, Tehnološko-metalurški fakultet, Univerzitet u Beogradu, (2020).
  • Sauerbrey, Verwendung von schwingquarzen zur wägung dünner schichten und zur mikrowägung. Zeitschrift für Physik 155, 206–222 (1959).
  • Kittle, D., Du, X., Jiang, F., Qian, C., Heinze, T., Roman, M. & Esker, A. R. Equilibrium water contents of cellulose films determined via solvent exchange and quartz crystal microbalance with dissipation monitoring. Biomacromolecules 12, 2881–2887 (2011).
  • Rojas, J. Cellulose chemistry and properties: Fibers, nanocelluloses and advanced materials. (Springer International Publishing, 2016).
  • Kanazawa, K. & Gordon, J. G. Frequency of a quartz microbalance in contact with liquid. Analytical Chemistry 57, 1770–1771 (1985).
  • Craig, S. J. & Plunkett, M. Determination of coupled solvent mass in quartz crystal microbalance measurements using deuterated solvents. Journal of Colloid and Interface Science 262, 126–129 (2003).
  • Mohan, , Spirk, S., Kargl, R., Doliška, A., Vesel, A., Salzmann, I., Resel, R., Ribitsch, V. & Stana-Kleinschek, K. Exploring the rearrangement of amorphous cellulose model thin films upon heat treatment. Soft Matter 8, 9807–9815 (2012).
  • Myllytie, , Salmi, J. & Laine, J. The influence of pH on the adsorption and interaction of chitosan with cellulose. BioResources 4, 1647–1662 (2009).
  • Hussain, , Khalaf, M., Adil, H., Zageer, D., Hassan, F., Mohammed, S. & Yousif, E. Metal complexes of Schiff’s bases containing sulfonamides nucleus: a review. Research Journal of Pharmaceutical, Biological and Chemical Sciences 7, 1008–1025 (2016).