3rd International Conference on Chemo and BioInformatics, Kragujevac, September 25-26. 2025. (pp. 239-242)
АУТОР(И) / AUTHOR(S): Tamara Erceg, Nevena Vukić, Dejan Kojić
Download Full Pdf 
DOI: 10.46793/ICCBIKG25.239E
САЖЕТАК / ABSTRACT:
Traditional plasticizers, predominantly phthalates, pose significant health and environmental risks due to their endocrine-disrupting properties and tendency to leach from products. In response, green plasticizers, sourced from renewable materials like vegetable oils and plant-based polyols, have emerged as a crucial, sustainable alternative. They offer reduced toxicity and biodegradability, making them ideal for sensitive applications like food packaging. Our research investigated the use of novel tartrate-based plasticizers, synthesized from glycerol and PET waste, in biodegradable active packaging. Studies showed that glycerol tritartrate significantly improved the mechanical and barrier properties of cellulose acetate (CA) and CA/polycaprolactone diol (PCL diol) blends, with a 7 wt% concentration providing an optimal balance. Additionally, a plasticizer from polyethylene terephthalate (PET) waste and tartaric acid demonstrated a dual role as both a plasticizer and a compatibilizer, enhancing film flexibility and barrier performance at concentrations of 30% and 20%, respectively. These findings confirm the viability of using green plasticizers to create high-performance, environmentally friendly packaging materials that address the sustainability challenges posed by the plastics industry.
КЉУЧНЕ РЕЧИ / KEYWORDS:
green plasticizers, tartarates, packaging, PET waste
ПРОЈЕКАТ / ACKNOWLEDGEMENT:
This research is funded by the Ministry of Science, Technological Development and Innovation, Republic of Serbia, grants no. 451-03-136/2025-03/200134 and 451-03- 136/2025-03/200132.
ЛИТЕРАТУРА / REFERENCES:
- D. Braun, H. Cherdron, H. Ritter., Polymer Synthesis: Theory and Practice: Fundamentals, Methods, Experiments; Springer: Heidelberg, Germany, 2001; 105–110.
- J. K. Sears, J.R. Darby., The Technology of Plasticizers; John Wiley: New York, NY, USA, 1982.
- T. Erceg, N. Vukić, O. Šovljanski, A. Stupar, V. Šergelj, M. Aćimović, S. Baloš, J. Ugarković, D. Šuput, S. Popović, S. Rakić., Characterization of Films Based on Cellulose Acetate/Poly(caprolactone diol) Intended for Active Packaging Prepared by Green Chemistry Principles, ACS Sustainable Chemistry and Engineering 10 (28) (2022) 9141–9154.
- T. Erceg, N. Vukić, O. Šovljanski, V. Teofilović, S. Porobić, S. Baloš, S. Kojić, P. Terek, B. Banjanin, S. Rakić, Preparation and characterization of biodegradable cellulose acetate-based films with novel plasticizer obtained by polyethylene terephthalate glycolysis intended for active packaging, Cellulose 30 (2023) 5825–5844.
