55. godišnja konferencije o aktuelnim problemima korišćenja i zaštite voda, Ivanjica, 25–27. maj 2026. [str. 269-278]
AUTHOR(S) / АУТОР(И): Andrej Race
, Neda Bošković
, Ivan Jerman 
Download Full Pdf 
DOI: https://doi.org/10.46793/VODA26.269R
ABSTRACT / САЖЕТАК:
Mikroplastika je sveprisutni zagađivač akvatičnih ekosistema, često akumulirana u sedimentima rijeka i jezera. Cilj ovog istraživanja je procena izazova i komparativna analiza hemijske identifikacije mikroplastike ekstrahovane iz sedimenta rijeka i jezera u Crnoj Gori, primenom Raman spektroskopije (manualna i automatska analiza) i FTIR ATR spektroskopije. Rezultati pokazuju da Raman spektroskopija omogućava detekciju manjih i kontaminiranih čestica, pružajući neinvazivne analize, ali je ograničena pojavom fluorescentnih smetnji i lošijim kvalitetom spektra kod nekih uzoraka. FTIR ATR, s druge strane, daje jasne i reproducibilne spektralne podatke za veće čestice, ali zahteva direktan kontakt sa uzorkom, što može dovesti do gubitka čestica. Kombinovana primena obe metode omogućava preciznu hemijsku karakterizaciju i pruža ključne uvide u ekološke implikacije mikroplastike.
KEYWORDS / КЉУЧНЕ РЕЧИ:
mikroplastika, hemijska identifikacija, Raman spektroskopija, FTIR ATR, sedimenti rijeka i jezera
ACKNOWLEDGEMENT / ПРОЈЕКАТ:
REFERENCES / ЛИТЕРАТУРA:
- Adhikari, S., Kelkar, V., Kumar, R., Halden, R.U. (2022). Methods and challenges in the detection of microplastics and nanoplastics: a mini‑review. Polymer International, 5, 543–551.
- Araujo, F.A., Nolasco, M.M., Ribiero A.M.P., Ribiero-Claro, P.J.A. (2018). Identification of microplastics using Raman spectroscopy: Latest developments and future prospects. Water research, 142, 426-440.
- Bajt, O. (2021). From plastics to microplastics and organisms, FEBS Open bio, 11(4), 954–966.
- Bošković, N., Jaćimović, Ž., Bajt, O. (2023). Microplastic pollution in rivers which belong to the Adriatic Sea basin in Montenegro: Impact on pollution of the Montenegrin coastline. Science of the Total Environment, 905:167206.
- Bošković, N., Jaćimović, Ž., Bajt, O. (2025). Protected natural areas are not protected from plastic pollution and its ecological risks: The case of Tara River in Montenegro, protected by UNESCO. Journal of Environmental Chemical Engineering, 13:117726.
- Cabernard, L., Roscher, L., Lorenz, C., Gerdts, G., Primpke S. (2018) Comparison of Raman and Fourier Transform Infrared Spectroscopy for the Quantification of Microplastics in the Aquatic Environment. Environmental Science & Technology 52 (22), 13279-13288.
- Coppock, R.L., Cole, M., Lindeque, P.K., Queirós, A.M., Galloway, T.S. (2017). A small‑scale, portable method for extracting microplastics from marine sediments. Environmental Pollution, 230, 829–837.
- Hurley, R.R., Lusher, A.L., Olsen, M., Nizzetto, L. (2018). Validation of a method for extracting microplastics from complex, organic‑rich, environmental matrices. Environmental Science & Technology, 52(13), 7409–7417.
- Ivleva, N. P. (2021). Chemical analysis of microplastics and nanoplastics: challenges, advanced methods, and perspectives. Chemical Reviews, 121(19), 11886–11936.
- Jeong, E., Lee, J.Y., Redwan, M. (2024) Animal exposure to microplastics and health effects: A review, Emerg. Contam. (4), 100369.
- Kaegi, R., Philipp, M., Jüngling, I.S., Ivleva, N.P., Bucheli, T.D. (2025) Quantification of small (1–10 µm) microplastic particles in soil matrices using automated scanning electron microscopy: possibilities and limitations, Anal Bioanal Chem. 417(27), 6191–6208.
- Koelmans, A.A., Mohamed Nor, N.H., Hermsen, E., Kooi, M., Mintenig, S.M. et al. (2019) Microplastics in freshwaters and drinking water: critical review and assessment of data quality, Water Res. 155, 410–422.
- Li, J., Liu, H., Paul Chen, J. (2018). Microplastics in freshwater systems: a review on occurrence, environmental effects, and methods for microplastics detection, Water reserch 137, 362–374.
- Li, J., Zhang, K., Zhang, H. (2018). Microplastics in sediments of the Changjiang Estuary, China. Environmental Pollution, 234, 286–292.
- Löder, M.G.J. and Gerdts, G. (2016). Analysis of environmental microplastics by vibrational microspectroscopy: FTIR, Raman or both? Analytical and Bioanalytical Chemistry, 408, 8377–8391.
- O’Brien, S., Rauert, C., Ribeiro, F., Okoffo, E.D., Burrows, S.D. et al. (2023) There’s something in the air: a review of sources, prevalence and behaviour of microplastics in the atmosphere, Sci. Total Environ. 874, 162193.
- Prata, J.C., da Costa, J.P., Lopes, I., Duarte, A.C., Rocha‑Santos, T. (2019). Environmental exposure to microplastics: An overview on possible human health effects. Science of The Total Environment, 702, 134455.
- Tanaka, K., Takada, H., Yamashita, R., Mizukawa, K., Fukuwaka, M. et al. (2013) Accumulation of plastic-derived chemicals in tissues of seabirds ingesting marine plastics, Marine Pollution Bulletin, 69 (1-2), 219–222.
- Thompson, R.C., Olsen, Y., Mitchell, R.P., Davis, A., Rowland, S.J., John, A.W., McGonigle, D., Russell, A.E., (2004). Lost at sea: where is all the plastic? Science 304, 838.
- Wang, L., Zu, B., Yang, Q., Guo, J., Li, J. (2023). Sources, distribution, and environmental effects of microplastics: a systematic review. RSC Advances, 13, 15566–15574.
- Xu, J., Tang, M., Xu, X.(2025) Microplastics in food: sources, distribution, health impacts, and regulation, J. Food Compos. Anal. 140, 107274.
- Yang, L., Zhang, Y., Kang, S., Wang, Z., Wu, C. (2021) Microplastics in soil: a review on methods, occurrence, sources, and potential risk, Sci. Total Environ. 780, 146546.
- Zhang, Y. and Xiong, X. (2025). Microplastics in aquatic ecosystems: A global review of distribution, ecotoxicological impacts, and human health risks. Water, 17(12), 1741.
