1st International Conference on Chemo and BioInformatics, ICCBIKG 2021, (157-160)
AUTHOR(S) / АУТОР(И): Petar B. Stanić, Nataša Vukićević, Vesna Cvetković, Miroslav Pavlović, Silvana B. Dimitrijević, Biljana Šmit
E-ADRESS / Е-АДРЕСА: petar.stanic@uni.kg.ac.rs, biljana. smit@uni.kg.ac.rs, vukicevic@ihtm.bg.ac.rs, v.cvetkovic@ihtm.bg.ac.rs, mpavlovic@ihtm.bg.ac.rs,silvana.dimitrijevic@irmbor.co.rs
DOI: 10.46793/ICCBI21.157S
ABSTRACT / САЖЕТАК:
Four 2-thiohydantoin derivatives were synthesized and their corrosion inhibition properties on mild steel (MS) in 0.5M HCl solution was evaluated using usual gravimetric and electrochemical methods (weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS). Morphology of the metal surface was characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The study has shown that these compounds provide good protection for mild steel against corrosion in the acidic medium.
KEY WORDS / КЉУЧНЕ РЕЧИ:
thiohydantoins, corrosion inhibition, mild steel, electrochemical measurements, surface analysis
REFERENCES / ЛИТЕРАТУРА:
- J. Harvey, F.C. Walsh, A.H. Nahle., A review of inhibitors for the corrosion of transition metals in aqeous liquids, J. Mol. Liq., 266 (2018) 160-175.
- H. Cho, S-H. Kim, D. Shin., Recent applications of hydantoin and tiohydantoin in medicinal chemistry, Eur. J. Med. Chem., 164 (2019) 517-545.
- a) L.O. Olasunkamni, B.P. Moloto, I.B. Obot, E.E. Ebenso., Anticorrosion studies of some hydantoin derivatives for mild steel in 0.5 M HCl solution: Experimental, quantum-chemical, Monte-Carlo simulations and QSAR studies, J. Mol. Liq., 252 (2018) 62-74. b) A.O. Yüce, G. Kardaş., Adsorbtion and inhibition effect of 2-thiohydantoin on mild steel corrosion in 0,1 M HCl, Corr. Sci., 58 (2012) 86-94.
- S. Kumar, S.L.A. Kumar, A. Sreekanth., Anticorrosion potential of 4-amino-3-methyl-1,2,4- triazole-5-thione derivatives (SAMTT and DBAMTT) on mild steel in hydrochloric acid solution, Ind. Eng. Chem. Res., 51 (2012) 5408-5418.
- Šmit, R.Z. Pavlović, A. Radosavljević-Mihailović, A. Došen, M.G. Ćurčić, D.S. Šeklić, M.N. Živanović., Synthesis, characterization and cytotoxicity of palladium(II) complex of 3-[(2-hydroxy- benzilidene)-amino]-2-thioxo-imidazolidin-4-one, J. Serb. Chem Soc., 78 (2013) 217-227.
- O. Yüce, G. Kardaş., Adsorption and inhibition effect of 2-thiohydantoin on mild steel corrosion in 0.1M HCl, Corros. Sci., 58 (2012) 86-94.